Only Liverpool's Mohamed Salah, against Rangers in 2022, has scored a quicker hat-trick in the competition.
Substitute Mehdi Taremi, who replaced the injured Chiquinho in the first half, hauled Olympiacos back into the match with an emphatic header past stand-in Madrid goalkeeper Andriy Lunin on 52 minutes.
The Ukraine international was filling in for Thibaut Courtois, who missed the trip due to illness.
Madrid had never won away to Greek opponents on seven previous visits but Mbappe ensured the Spanish giants put an end to that sequence, turning in his fourth of the night after excellent work by Vinicius down the left.
That took Mbappe to nine goals in five Champions League matches this term, sending him three clear of Victor Osimhen at the top of the scoring charts.


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